(1,5-Cyclooctadiene)[3-methyl-1-[(2-pyridyl)methyl]-imidazol-2-ylidine] iridium(I) triflate

$150.00

(1,5-cyclooctadiene)[3-methyl-1-[(2-pyridyl)methyl]-imidazol-2-ylidine] iridium(I) triflate (100 mg)

 

In stock (can be backordered)

Description

Other names N/A
Chemical formula C19H23F3IrN3O3S
Molecular weight 622.68 g / mol
CAS # 1883459-62-8
Purity > 97%
Catalog # 02-02-0011
Appearance Bright red-orange powder
SDS Download now
Package quantity 100 mg

Developed in the laboratories of our cofounder Prof. Travis Williams, this iridium complex is a potent catalyst for the acceptorless dehydrogenation of primary alcohols to carboxylic acids and carboxylates (DOI: 10.1021/acscatal.8b00105). It can be used in neat alcohol (DOI: 10.1021/acscatal.5b02732).

The catalyst is effective at loadings as low as 50 mol ppm and provides turnover numbers as high as 16000.